Solvent and Substituent Effects on the Phosphine + CO2 Reaction
نویسندگان
چکیده
منابع مشابه
Reaction Constants Derived from Activation Parameters for the Evaluation of Substituent and Solvent Effects
Internet Electron. J. Mol. Des. 2003, 1, 000–000 Abstract In order to separate the effect of substituents into two parts, referring to the interaction of the reacting molecules and the solvation, the δ∆G, δ∆H and δ∆S reaction constants were defined and determined from the dependence of ∆G, ∆H and ∆S activation parameters on the σ substituent constants, by analogy with the Hammett equation. The ...
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ژورنال
عنوان ژورنال: Inorganics
سال: 2018
ISSN: 2304-6740
DOI: 10.3390/inorganics6040110